SteelAnodize.com

A patent-pending process to electrochemically grow an attractive and protective oxide layer on steel. This is an attractive solution to prevent fresh water staining of steel coils.
For more information or licensing, please contact:

Prof. T. David Burleigh, PhD & PE
Materials & Metallurgical Engineering Dept.
New Mexico Tech, Socorrro, NM 87801 USA
1-575-835-5831, burleigh(at)nmt.edu
www.nmt.edu/~burleigh/



Images from the SteelAnodize process:


The dichroic oxide film has been grown on 1010 steel in 1 minute increments in 50% KOH solution at 70 C and +2.0 V vs. the steel counter electrode. (Fig 4 in Burleigh et al [2]).

A Damascus steel knife blade has been etched and then steelanodized. The different compositions of steel and the different heat treatments reflect different colors.



A dichroic knife blade made from layered carbon steel has been steelanodized. The steel layers have different compositions, which grow different oxide thicknesses, and therefore reflect different colors, giving the steel the rainbow appearance.




The anodizing requires a hot caustic electrolyte and a DC power supply [1,2].




SEM cross-section of the anodic film grown on steel at 50 C and +2.2 V. (Fig 3a in Burleigh et al [3]).




FESEM of the fractured oxide (70 C and +2.5 V) showing the nano-porous hollow channels. (Fig 8a in Burleigh et al [3]).





A model of the nano-porous magnetite (Fe3O4) channels which compose the anodic oxide. (Fig 10 in Burleigh et al [3]).




The steelanodizing provides corrosion protection against pure water. The four steel panels are shown after four weeks of partial immersion in 100 mL 18 MegaOhm-cm water after the water had evaporated. The far left panel was wet polished to 600 grit SiC prior to testing. The middle left panel was partially steelanodized. The two right panels were fully steelanodized at 50 C and +3.0 V, and at 70 C and +2.1 V respectively. (related to Fig 17 in Burleigh et al [3]).





The steelanodizing provides corrosion protection against aerated saltwater if the pores are sealed with WD-40. The graph shows the reduction in the corrosion rate of steel with the different surface treatments. (Fig 18 in Burleigh et al [3]).





The steelanodizing can provide a large variety of different oxide films, depending on the temperature and the applied voltage. (Fig 1 in Burleigh et al [3]).

References:

1. T.D. Burleigh, T.C. Dotson, K.T. Dotson, "Method of Anodizing Steel," (filed on January 17, 2007, U.S. application number 11/624,137.) Publication number US-2008-0169200-A1 on 07/17/2008.

2. T.D. Burleigh, T.C. Dotson, K.T. Dotson, S.J. Gabay, T. Sloan, S.G. Ferrell, "Anodizing Steel in KOH and NaOH Solutions," Journal of the Electrochemical Society (Oct. 2007), 154, 10, 579-586. AnodizedJECS2007.pdf

3. T.D. Burleigh, P. Schmuki and S. Virtanen, "Properties of the Nanoporous Anodic Oxide Electrochemically Grown on Steel in Hot 50% NaOH." Journal of the Electrochemical Society, (Jan 2009), 156, 1, C45-C53. ECS_Burleigh2009.pdf
For more information or for licensing, please contact Dr. T.D. Burleigh at: burleigh(at)nmt.edu

Related links: "Burleigh Corrosion Consultants LLC," webpage: www.corrosionhelp.com


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